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Results of potential ecological risk assessment indicated that combining ZnCl2 impregnation and co-pyrolysis had great potential to reduce the ecological risk of heavy metals in sewage sludge derived biochar.The properties of sulfidated zero-valent iron (S-ZVI) are considered to be determined by the entire structure of Fe0 and FexSy as a whole, but few studies focus on the influence of the morphology and structure of the external FexSy layer on the performance of S-ZVI. In this study, after the sulfidation of microscale ZVI i