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Due to their widespread use, organophosphate esters (OPEs) are commonly detected in various environmental matrices and have been identified as emerging contaminants. In this review article, the occurrence and analytical techniques of OPEs in the biotic environment have been compiled and reviewed. Data from studies published the last decade all over the world covering a variety of species in trophic chain have been synthesized and evaluated. OPEs are among the most frequent detected flame retardants and high concentrations are detected in