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On the basis of the luminescent response of analytes, 5 response modes are obtained and 12 inorganic anions are classified into 6 groups. The sensing mechanisms are discussed in detail. Detection limits of typical anions Cr2O72-, PO43-, ClO-, and NO2- are calculated as 2.895 × 10-8, 6.353 × 10-6, 1.134 × 10-5, and 4.56 × 10-4 mol/L, respectively. Furthermore, the RGB@TLU-2 also shows the ability to distinguish 4 (Fe3+, Fe2+, Cu2+ and Cr3+) of 12 metal ions and 3 (Trp, Pro, and Arg) of 11 amino acids.High flux microchannel membranes have the potential for la