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40 to 0.62-1.12), implying more heterogeneous sorption of PhACs in soil-DOM binary systems. Sorption competition of DOM molecules with sulfadiazine and caffeine mostly contributed to their decreased soil sorption when DOM was present. In contrast, the formation of DOM-atenolol associates in the solution phase caused the largely decreased soil sorption of atenolol in the presence of DOM. It is suggested that DOM concentration (e.g., ≥ 60 mg C L-1) and its interaction with PhACs should be taken into consideration when assessing the enviro