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The interfacial properties of ultrahigh methoxylated pectin (UHMP) ready via esterification of citrus pectin (CP) had been investigated. The intrinsic viscosity ([η]) of pectin was considerably reduced from 1211.5 mL/g to 294.9 mL/g whilst the degree of methylation (DM) increased from 63.18 ± 0.08% to 91.52 ± 0.11%. Surface stress (γ) analysis suggested that UHMP had a vital micelle concentration (CMC) of 0.8 g/L, that was somewhat smaller