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The presence of autoimmune events were recorded in patients receiving immunecheckpoint inhibitors. Retrospective study in patients receiving immune checkpoint inhibitors (ICIs) during the period of 2012-2019. A total of 554patients received ICIs of which 123 developed an immune related adverse event. Twenty one (17%) with toxicity were identified as having apre-existing autoimmune disease and 88 required treatment with corticosteroids or hormone replacement. Thirty two (26%) out of 123 had to temporarilydiscontinue ICIsdue to autoimmune

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Furthermore, the limitations of current spectroscopic approaches for the exploration of NOM-related environmental processesand how these weaknesses/drawbacks can be addressed are explored. Finally, suggestions and directions are proposed to advance the development of spectroscopic methods in analyzing and elucidating the properties and behaviors of NOM in natural and engineered environments.Interests in the kinetics of radical-induced reactions in aqueous solution have grown remarkably due to their water engineering significance (e.g