https://www.selleckchem.com/pr....oducts/itacitinib-in
Synthesis and properties of anthracene-based cyclic π-clusters which possess two and four anthracene units are discussed. The optimal cyclization conditions were determined based on a nickel(-mediated reaction that afforded a cyclic anthracene dimer as the major product. Bringing two anthracene planes in close proximity in a face-to-face manner resulted in red-shifted absorption owing to the narrowing of the HOMO-LUMO gap. The cyclic anthracene dimer exhibits multi-stimuli responsiveness due to high π-congestion. For exam
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