https://www.selleckchem.com/pr....oducts/Temsirolimus.
In short, this study shows that photochemical cleavage of metal-metal bonds (Pd, Pt) via excitation to an M-M antibonding orbital facilates disproportionation of the MIII-MIII complex to MII and MIV complexes.The site-selective C-H oxidation of terpenoids by P450 attracts great attention because of their wide range of biological activities. However, the binding and catalytic mechanism of P450 for the hydroxylation of complex terpenoid substrates remains elusive, which has limited the rational engineering of P450 as a biocatalyst fo
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