https://www.selleckchem.com/pr....oducts/qnz-evp4593.h
The cyclometalated Pt(ii) acetylide derivative with a 1,3-bis(N-octyl-benzimidazol-2-yl)benzene (N^C^N) ligand and a free terpyridine (TPY) receptor has been successfully synthesized and characterized. X-ray crystallography shows its inefficient conjugation degree between the [(N^C^N)Pt] and TPY planes. #link# This bifunctional complex shows an enhanced 1MLCT/LLCT absorption band (ε = 3.30 × 104 dm3 mol-1 cm-1) centered at λmax = 365 nm, and the well-resolved vibronic-structured 3MLCT/LLCT emission bands (Φ = 0.08, τ = 3.43 μs) in t
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