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Enhancement of photoexcited charge separation in semiconductor photocatalysts is one of the important subjects to improve the efficiency of energy conversion for photocatalytic overall water splitting into H2 and O2. In this study, we report an efficient separation of photoexcited charge at the interface between non-doped pure CeO2 and Y3+-doped CeO2 phases on particle surfaces with heterogeneous doping structure. Neither non-doped pure CeO2 and homogeneously Y3+-doped CeO2 gave activities for photocatalytic H2 and O2 production under u
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